AC Milan have been paired with PSV during Friday's draw for the 2013-14 Champions League play-offs in Nyon, Switzerland, world media report.
England's Arsenal will have to compete with Turkey's Fenerbahce if they are to reach the group stages of the competition.
Olympique Lyonnais meet last year's Primera Division surprise package Real Sociedad, while Schalke take on Ukrainian side Metalist Karkiv and Pacos Ferreira face Zenit St Petersburg in the fifth and last tie of the league route.
In the Champions Route, Scottish champions Celtic will have to compete with Kazakhstan's Shakhter Karagandy, while last year's Europa League semi-finalists Basel will play with Bulgaria's Ludogorets.
